Document Type

Article

Publication Date

Fall 9-2022

Publication Title

ACS Applied Materials & Interfaces

Abstract

This paper implements molecular dynamics (MD) simulation using reactive force field (ReaxFF) to evaluate the

atomistic origin of the interfacial behavior in the overmolded hybrid unidirectional continuous carbon fiber low-melt PAEK (CFR- LMPAEK)-short carbon fiber reinforced PEEK (SFR-PEEK) polymer composites. From the MD simulation, it was observed that the

interfacial properties improve with increasing maximum processing temperature and injection pressure although such an improving trajectory gets saturated beyond specific limits. The interfacial strength and fracture response of the hybrid polymer system at the interface are also evaluated. The mechanical responses obtained from MD simulation are used as adhesive properties in the macroscale finite element analysis (FEA)-based single lap joint (SLJ) model where the interfacial behavior between the adherends (CFR-LMPAEK and SFR-PEEK) is implemented using cohesive zone model (CZM). The simulated FE results show a good correlation with the SLJ experimental data. Thus, by linking the interfacial properties at the molecular scale to the performance of the interfacial bond at the macroscale, the comprehensive approach presented here opens up various efficient avenues toward atomistically engineered performance tuning in hybrid overmolded fiber-reinforced polymer composites to meet desired large-scale performance needs.

Keywords

fusion bonding, interfacial strength, thermoplastic polymer, molecular dynamics, finite element analysis, multiscale, single lap joint

Volume

14

Issue

38

First Page

43666

Last Page

43680

DOI

https://doi.org/10.1021/acsami.2c09881

ISSN

1944-8252

Rights

This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Applied Materials & Interfaces, Copyright © 2022 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/acsami.2c09881

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